Direct synthesis of 1,6-anhydro sugars from unprotected glycopyranoses by using 2-chloro-1,3-dimethylimidazolinium chloride

Tomonari Tanaka, Wei Chun Huang, Masato Noguchi, Atsushi Kobayashi, Shin ichiro Shoda

研究成果: Article査読

72 被引用数 (Scopus)

抄録

Various 1,6-anhydro sugars have been synthesized directly from the corresponding unprotected glycopyranoses in excellent yields by using 2-chloro-1,3-dimethylimidazolinium chloride (DMC) as a dehydrative condensing agent. The reactions took place smoothly under mild reaction conditions in aqueous media. The present method would be a practical tool for synthesis of 1,6-anhydro derivatives of monosaccharides, linear-oligosaccharides, and branched-oligosaccharides.

本文言語English
ページ(範囲)2154-2157
ページ数4
ジャーナルTetrahedron Letters
50
18
DOI
出版ステータスPublished - 2009 5月 6
外部発表はい

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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