Direct observation of a lattice-framework silylene: A planar four-membered-ring dialkylsilylene with a small HOMO-LUMO energy gap

Eunsang Kwon, Hiromasa Tanaka, Takayuki Makino, Shinobu Tsutsui, Shigeki Matsumoto, Yusaburo Segawa, Kenkichi Sakamoto

研究成果: Article査読

4 被引用数 (Scopus)

抄録

The n-p transition of the lattice-framework silylene 2,3,4,6,7,8-hexa-tert- butyl-1,5-disilatricyclo[4.2.0.01,4]octa-2,7-diene-5,5-diyl was observed by differential transmission spectroscopy at 764 nm. The significantly red-shifted n-p transition of the silylene is caused by the planar four-membered Si2C2 ring containing the divalent silicon atom.

本文言語English
ページ(範囲)1325-1328
ページ数4
ジャーナルOrganometallics
25
5
DOI
出版ステータスPublished - 2006 2 27
外部発表はい

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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