Direct observation of a lattice-framework silylene: A planar four-membered-ring dialkylsilylene with a small HOMO-LUMO energy gap

Eunsang Kwon; Hiromasa Tanaka; Takayuki Makino; Shinobu Tsutsui; Shigeki Matsumoto; Yusaburo Segawa; Kenkichi Sakamoto

doi:10.1021/om0507023

Direct observation of a lattice-framework silylene: A planar four-membered-ring dialkylsilylene with a small HOMO-LUMO energy gap

Eunsang Kwon, Hiromasa Tanaka, Takayuki Makino, Shinobu Tsutsui, Shigeki Matsumoto, Yusaburo Segawa, Kenkichi Sakamoto

研究成果: Article › 査読

4 被引用数 (Scopus)

抄録

The n-p transition of the lattice-framework silylene 2,3,4,6,7,8-hexa-tert- butyl-1,5-disilatricyclo[4.2.0.0^1,4]octa-2,7-diene-5,5-diyl was observed by differential transmission spectroscopy at 764 nm. The significantly red-shifted n-p transition of the silylene is caused by the planar four-membered Si₂C₂ ring containing the divalent silicon atom.

本文言語	English
ページ（範囲）	1325-1328
ページ数	4
ジャーナル	Organometallics
巻	25
号	5
DOI	https://doi.org/10.1021/om0507023
出版ステータス	Published - 2006 2 27
外部発表	はい

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

文献へのアクセス

10.1021/om0507023

フィンガープリント「Direct observation of a lattice-framework silylene: A planar four-membered-ring dialkylsilylene with a small HOMO-LUMO energy gap」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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AU - Tsutsui, Shinobu

AU - Matsumoto, Shigeki

AU - Segawa, Yusaburo

AU - Sakamoto, Kenkichi

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