Direct evidence of cation disorder in thermoelectric lead chalcogenides PbTe and PbS

Sofie Kastbjerg, Niels Bindzus, Martin Søndergaard, Simon Johnsen, Nina Lock, Mogens Christensen, Masaki Takata, Mark A. Spackman, Bo Brummerstedt Iversen

研究成果: Article査読

78 被引用数 (Scopus)

抄録

The extraordinary thermoelectric properties of lead chalcogenides have attracted huge interest in part due to their unexpected low thermal conductivity. Here, it is shown that anharmonicity and large cation disorder are present in both PbTe and PbS, based on elaborate charge density visualization using synchrotron powder X-ray diffraction (SPXRD) data analyzed with the maximum entropy method (MEM). In both systems, the cation disorder increases with increasing temperature, whereas the Te/S anions appear to be centered on the expected lattice positions. Even at the lowest temperatures of 105 K, the lead ion is on average displaced by ≈0.2 Å from the rock-salt lattice position, creating a strong phonon scattering mechanism. These findings provide a clue to understanding the excellent thermoelectric performance of crystals with atomic disorder. The SPXRD-MEM approach can be applied in general opening up for widespread characterization of subtle structural features in crystals with unusual properties.

本文言語English
ページ(範囲)5477-5483
ページ数7
ジャーナルAdvanced Functional Materials
23
44
DOI
出版ステータスPublished - 2013 11 26
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 生体材料
  • 凝縮系物理学
  • 電気化学

フィンガープリント

「Direct evidence of cation disorder in thermoelectric lead chalcogenides PbTe and PbS」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル