Direct dry syntheses and thermal analyses of a series of aluminum complex hydrides

T. Sato, K. Ikeda, H. W. Li, H. Yukawa, M. Morinaga, S. Orimo

研究成果: Article査読

17 被引用数 (Scopus)

抄録

Synthesis of a series of aluminum complex hydrides, namely, LiAlH 4, Li3AlH6, NaAlH4, Na 3AlH6, Mg(AlH4)2, MgAlH5, Ca(AlH4)2, and CaAlH5, was attempted by the mechanochemical milling of A1H3 and the other elemental hydrides. Aluminum complex hydrides, except MgAlH5, were synthesized, and their dehydriding (decomposition) properties were systematically investigated by thermogravimetry. The dehydridng temperatures possibly showed a correlation with the geometrical distances in space between M' (Ḿ) and H in the crystal structures of the aluminum complex hydrides.

本文言語English
ページ(範囲)182-186
ページ数5
ジャーナルMaterials Transactions
50
1
DOI
出版ステータスPublished - 2009 1

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学
  • 材料力学
  • 機械工学

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