Direct dry syntheses and thermal analyses of a series of aluminum complex hydrides

T. Sato, K. Ikeda, H. W. Li, H. Yukawa, M. Morinaga, S. Orimo

研究成果: Article

16 引用 (Scopus)

抜粋

Synthesis of a series of aluminum complex hydrides, namely, LiAlH 4, Li3AlH6, NaAlH4, Na 3AlH6, Mg(AlH4)2, MgAlH5, Ca(AlH4)2, and CaAlH5, was attempted by the mechanochemical milling of A1H3 and the other elemental hydrides. Aluminum complex hydrides, except MgAlH5, were synthesized, and their dehydriding (decomposition) properties were systematically investigated by thermogravimetry. The dehydridng temperatures possibly showed a correlation with the geometrical distances in space between M' (Ḿ) and H in the crystal structures of the aluminum complex hydrides.

元の言語English
ページ(範囲)182-186
ページ数5
ジャーナルMaterials Transactions
50
発行部数1
DOI
出版物ステータスPublished - 2009 1 1

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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