Direct conversion of blast furnace gas to dimethyl ether over Cu-ZnO-Ga2O3/γ-Al2O3 hybrid catalyst: Optimum mass ratio of the catalyst

Satoshi Machida, Tomohiro Akiyama, Atsushi Muramatsu, Jun Ichiro Yagi

研究成果: Article査読

5 被引用数 (Scopus)

抄録

The objective of this study is to develop a catalyst in a packed-bed reactor for direct synthesis of dimethyl ether ((CH3)2O, DME) from blast furnace offgas (CO-CO2-H2-N2, BFG). Physically-admixed (hybrid) catalysts of Cu-ZnO-Ga2O3 for CH3OH synthesis and γ-Al2O3 for its dehydration were experimentally studied, in which the influence of mixing ratio of the two catalysts on both yield and selectivity of DME was mainly examined for the same catalyst mass. The results showed that the developed hybrid catalyst is very effective in producing DME directly from BFG without equilibrium limit of methanol. Interestingly, the yield of DME had a significant dependence of mixing ratio, and the hybrid catalyst with only 5 mass% γ-Al2O3 showed the highest yield with 99.3% selectivity of DME+methanol. This implies that methanol formation governs the rate of this series reaction (BFG→CH3OH→DME) due to fast dehydration of methanol to DME.

本文言語English
ページ(範囲)531-535
ページ数5
ジャーナルIsij International
37
5
DOI
出版ステータスPublished - 1997

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

フィンガープリント 「Direct conversion of blast furnace gas to dimethyl ether over Cu-ZnO-Ga<sub>2</sub>O<sub>3</sub>/γ-Al<sub>2</sub>O<sub>3</sub> hybrid catalyst: Optimum mass ratio of the catalyst」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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