Dielectric anisotropy of a homochiral trinuclear nickel(II) complex

Da Wei Fu; Yu Mei Song; Guo Xi Wang; Qiong Ye; Ren Gen Xiong; Tomoyuki Akutagawa; Takayoshi Nakamura; Philip Wai Hong Chan; Songping D. Huang

doi:10.1021/ja0701816

Dielectric anisotropy of a homochiral trinuclear nickel(II) complex

Da Wei Fu, Yu Mei Song, Guo Xi Wang, Qiong Ye, Ren Gen Xiong, Tomoyuki Akutagawa, Takayoshi Nakamura, Philip Wai Hong Chan, Songping D. Huang

研究成果: Article › 査読

174 被引用数 (Scopus)

抄録

Hydrothermal reaction of (S)-1,1′1″-2,4,6-trimethylbenzene-1,3,5-triyl-tris(methylene)-tris-pyrrolidine-2-carboxylic acid (TBPLA) with Ni(ClO₄)₂·6H₂O gave pale green block crystals of 1. X-ray crystal structure analysis showed the complex to be a trinuclear descrete homochiral molecule with each Ni center sitting in distorted octahedron geometries. Anisotropic permittivity measurements reveal that 1 exhibits huge dielectric anisotropy along its three different crystal axes that is ca. 3.5 times of ε_r (E//c)/ε_r (E//b) with temperature and frequency independence.

本文言語	English
ページ（範囲）	5346-5347
ページ数	2
ジャーナル	Journal of the American Chemical Society
巻	129
号	17
DOI	https://doi.org/10.1021/ja0701816
出版ステータス	Published - 2007 5月 2
外部発表	はい

ASJC Scopus subject areas

触媒
化学 (全般)
生化学
コロイド化学および表面化学

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10.1021/ja0701816

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title = "Dielectric anisotropy of a homochiral trinuclear nickel(II) complex",

abstract = "Hydrothermal reaction of (S)-1,1′1″-2,4,6-trimethylbenzene-1,3,5-triyl-tris(methylene)-tris-pyrrolidine-2-carboxylic acid (TBPLA) with Ni(ClO4)2·6H2O gave pale green block crystals of 1. X-ray crystal structure analysis showed the complex to be a trinuclear descrete homochiral molecule with each Ni center sitting in distorted octahedron geometries. Anisotropic permittivity measurements reveal that 1 exhibits huge dielectric anisotropy along its three different crystal axes that is ca. 3.5 times of εr (E//c)/εr (E//b) with temperature and frequency independence.",

author = "Fu, {Da Wei} and Song, {Yu Mei} and Wang, {Guo Xi} and Qiong Ye and Xiong, {Ren Gen} and Tomoyuki Akutagawa and Takayoshi Nakamura and Chan, {Philip Wai Hong} and Huang, {Songping D.}",

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T1 - Dielectric anisotropy of a homochiral trinuclear nickel(II) complex

AU - Fu, Da Wei

AU - Song, Yu Mei

AU - Wang, Guo Xi

AU - Ye, Qiong

AU - Xiong, Ren Gen

AU - Akutagawa, Tomoyuki

AU - Nakamura, Takayoshi

AU - Chan, Philip Wai Hong

AU - Huang, Songping D.

PY - 2007/5/2

Y1 - 2007/5/2

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AB - Hydrothermal reaction of (S)-1,1′1″-2,4,6-trimethylbenzene-1,3,5-triyl-tris(methylene)-tris-pyrrolidine-2-carboxylic acid (TBPLA) with Ni(ClO4)2·6H2O gave pale green block crystals of 1. X-ray crystal structure analysis showed the complex to be a trinuclear descrete homochiral molecule with each Ni center sitting in distorted octahedron geometries. Anisotropic permittivity measurements reveal that 1 exhibits huge dielectric anisotropy along its three different crystal axes that is ca. 3.5 times of εr (E//c)/εr (E//b) with temperature and frequency independence.

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Dielectric anisotropy of a homochiral trinuclear nickel(II) complex

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