Development of diastereoselective birch reduction-alkylation reactions of bi- and tricyclic β-alkoxy-α,β-unsaturated ketones

Kou Hiroya, Yusuke Ichihashi, Ai Furutono, Kiyofumi Inamoto, Takao Sakamoto, Takayuki Doi

研究成果: Article査読

11 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Diastereoselective Birch reduction-alkylation reactions of bicyclic β-alkoxy-α,β-unsaturated carbonyl compounds and tricyclic analogues were investigated. Although the relative configuration of the product was altered according to the structure of the starting material, stereoselectivity of the reaction could be accounted for by similar reaction pathways. The product from the tricyclic β-alkoxy-α, β-unsaturated carbonyl compound corresponded to the trichothecene skeleton.

本文言語English
ページ(範囲)6623-6630
ページ数8
ジャーナルJournal of Organic Chemistry
74
17
DOI
出版ステータスPublished - 2009 9月 4

ASJC Scopus subject areas

  • 有機化学

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