Design and synthesis of helically chiral spirocyclic P3 phosphazenes and characterization of their onium salts

Masahiro Terada, Kengo Goto, Masafumi Oishi, Tadahiro Takeda, Eunsang Kwon, Azusa Kondoh

研究成果: Article査読

10 被引用数 (Scopus)

抄録

Helically chiral spirocyclic P3 phosphazenes were designed as a novel family of chiral organosuperbases. The newly designed chiral P3 phosphazenes were synthesized from commercially available sources in several steps and characterized by X-ray crystallographic analysis of their onium salts. The optically pure P3 phosphazenium salt was obtained by using preparative chiral stationary phase HPLC and the absolute configuration of the helical chirality was determined.

本文言語English
ページ(範囲)2531-2534
ページ数4
ジャーナルSynlett
24
19
DOI
出版ステータスPublished - 2013

ASJC Scopus subject areas

  • Organic Chemistry

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