TY - JOUR
T1 - Densities at pressures up to 200 MPa and atmospheric pressure viscosities of ionic liquids 1-ethyl-3-methylimidazolium methylphosphate, 1-ethyl-3-methylimidazolium diethylphosphate, 1-butyl-3-methylimidazolium acetate, and 1-butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide
AU - Hiraga, Yuya
AU - Kato, Aya
AU - Sato, Yoshiyuki
AU - Smith, Richard L.
N1 - Publisher Copyright:
© 2015 American Chemical Society.
PY - 2015/3/12
Y1 - 2015/3/12
N2 - High pressure densities at (10-200) MPa over a range of temperatures and atmospheric pressure viscosities at (293-373) K for three ionic liquids (ILs) that are able to dissolve biomass, 1-ethyl-3-methylimidazolium methylphosphate ([emim][MP]), 1-ethyl-3-methylimidazolium diethylphosphate ([emim][DEP]), and 1-butyl-3-methylimidazolium acetate ([bmim][Ac]) are reported. Densities of the IL 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([bmim][Tf2N]) were measured at the same conditions to verify the apparatus and to extend the range of present data. The high pressure densities of [emim][MP] and [emim][DEP] are newly measured in this work. Combined expanded uncertainties of densities for [emim][MP], [emim][DEP], [bmim][Ac], and [bmim][Tf2N] were estimated to be 1.5 kg·m-3, 1.4 kg·m-3, 1.4 kg·m-3, and 1.7 kg·m-3, respectively. The Tait equation could correlate the experimental density data to within 0.03 % of average relative deviation. The derivative properties, isobaric expansivity, and isothermal compressibility were calculated using the Tait equation and it was observed that the isobaric expansivity decreased with increasing temperature. The trend of the isobaric expansivity and isothermal compressibility with temperature were in accordance with the theory of corresponding states using methanol for comparison.
AB - High pressure densities at (10-200) MPa over a range of temperatures and atmospheric pressure viscosities at (293-373) K for three ionic liquids (ILs) that are able to dissolve biomass, 1-ethyl-3-methylimidazolium methylphosphate ([emim][MP]), 1-ethyl-3-methylimidazolium diethylphosphate ([emim][DEP]), and 1-butyl-3-methylimidazolium acetate ([bmim][Ac]) are reported. Densities of the IL 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([bmim][Tf2N]) were measured at the same conditions to verify the apparatus and to extend the range of present data. The high pressure densities of [emim][MP] and [emim][DEP] are newly measured in this work. Combined expanded uncertainties of densities for [emim][MP], [emim][DEP], [bmim][Ac], and [bmim][Tf2N] were estimated to be 1.5 kg·m-3, 1.4 kg·m-3, 1.4 kg·m-3, and 1.7 kg·m-3, respectively. The Tait equation could correlate the experimental density data to within 0.03 % of average relative deviation. The derivative properties, isobaric expansivity, and isothermal compressibility were calculated using the Tait equation and it was observed that the isobaric expansivity decreased with increasing temperature. The trend of the isobaric expansivity and isothermal compressibility with temperature were in accordance with the theory of corresponding states using methanol for comparison.
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U2 - 10.1021/je5009679
DO - 10.1021/je5009679
M3 - Article
AN - SCOPUS:84924715623
SN - 0021-9568
VL - 60
SP - 876
EP - 885
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 3
ER -