Cyclic voltammetry and AC impedance of MmNi3.55Co0.75Mn0.4Al0.3 alloy single-particle electrode for rechargeable Ni/MH battery

M. Mohamedi, Tsugio Sato, Takashi Itoh, M. Umeda, I. Uchida

研究成果: Article査読

14 被引用数 (Scopus)

抄録

Voltammetry and ac impedance techniques were run on a single particle of MmNi3.55Co0.75Mn0.4Al0.3 alloy electrode with the aim of refining the investigating of the kinetics of the hydrogen adsorption-absorption processes into mischmetal alloys. The experimental impedance spectra for the hydrogen adsorption/absorption are similar in shape and in accordance with the theoretical predictions. Data were analyzed using an equivalent circuit based on the knowledge of the different processes taking place in the metal hydride electrodes. The model fitted the experimental data remarkably well. The equivalent circuit considers the charge-transfer reaction, the hydrogen transition between the adsorbed and absorbed states, and the impedance of finite hydrogen diffusion into the metal hydride electrode particle with spherical symmetry. The values of the obtained diffusion coefficient of hydrogen in the solid phase were 8.7-9 × 10-8 cm2 s-1 for the hydrogenation and dehydrogenation processes, respectively.

本文言語English
ジャーナルJournal of the Electrochemical Society
149
8
DOI
出版ステータスPublished - 2002 8 1

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 再生可能エネルギー、持続可能性、環境
  • 表面、皮膜および薄膜
  • 電気化学
  • 材料化学

フィンガープリント

「Cyclic voltammetry and AC impedance of MmNi<sub>3.55</sub>Co<sub>0.75</sub>Mn<sub>0.4</sub>Al<sub>0.3</sub> alloy single-particle electrode for rechargeable Ni/MH battery」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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