Crystal structures and thermoelectric properties of Ru1-xRe xSiy chimney-ladder compounds

Akira Ishida, Norihiko L. Okamoto, Kyosuke Kishida, Katsushi Tanaka, Haruyuki Inui

研究成果: Conference article査読

6 被引用数 (Scopus)

抄録

The phase relationship of Re-alloyed Ru2Si3 and the variations of the crystal structures and thermoelectric properties of the Ru1-xRexSiy chimney-ladder phases have been studied as a function of the Re concentration. The Ru1-xRe xSiy chimney-ladder phases are formed in a wide compositional range. Compositional formula of the chimney-ladder phases are determined to be Rui1-xRexSi1.539+0.178x (0.14 < x ≤ 0.76), which are systematically deviated from the idealized composition conforming the valence electron counting rule: VEC=14. Measurements of thermoelectric properties of single crystals with different compositions reveal that the chimney-ladder phases exhibit n-type semiconducting behavior at low Re concentrations and p-type semiconducting behavior at high Re concentrations. These results suggest that the VEC=14 rule can be used for predicting the semiconducting behavior of the chimney-ladder phases through the adjustment of VEC values by substituting elements, producing p-type semiconductors for VEC<14 and n-type for VEC>14, with the carrier concentration related to the deviation from VEC=14.

本文言語English
ページ(範囲)235-240
ページ数6
ジャーナルMaterials Research Society Symposium Proceedings
980
出版ステータスPublished - 2007 6 29
外部発表はい
イベント2006 MRS Fall Meeting - Boston, MA, United States
継続期間: 2006 11 272006 11 29

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学
  • 材料力学
  • 機械工学

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