TY - JOUR
T1 - Crystal structure of silver carbonate iodide Ag10(CO3)3I4
AU - Suzuki, Ryoji
AU - Watanabe, Yuta
AU - Yamane, Hisanori
AU - Kitaura, Mamoru
AU - Uchida, Kento
AU - Matsushima, Yuta
N1 - Funding Information:
Funding for this research was provided by: Murata Science Foundation (grant No. H30-95).
Publisher Copyright:
© 2021 International Union of Crystallography. All rights reserved.
PY - 2021/7/1
Y1 - 2021/7/1
N2 - The title silver carbonate iodide, Ag10 (CO3)3I4, decasilver(I) tris(carbonate) tetraiodide, was recently reported as a precursor of the new superionic conductor Ag17 (CO3)3I11. Ag10 (CO3)3I4, was prepared by heating a stoichiometric powder mixture of AgI and Ag2CO3 at 430 K. A single-crystal suitable for X-ray diffraction analysis was obtained by slow cooling of a melt with an AgI-rich composition down from 453 K. Ag10 (CO3)3I4 exhibits a layered crystal structure packed along [101], in which Ag atoms are intercalated between the layers of hexagonally close-packed I atoms, and CO3 groups. Up to now, Cs3Pb2 (CO3)3I is the only other compound containing carbonate groups and iodide ions registered in the Inorganic Crystal Structure Database.
AB - The title silver carbonate iodide, Ag10 (CO3)3I4, decasilver(I) tris(carbonate) tetraiodide, was recently reported as a precursor of the new superionic conductor Ag17 (CO3)3I11. Ag10 (CO3)3I4, was prepared by heating a stoichiometric powder mixture of AgI and Ag2CO3 at 430 K. A single-crystal suitable for X-ray diffraction analysis was obtained by slow cooling of a melt with an AgI-rich composition down from 453 K. Ag10 (CO3)3I4 exhibits a layered crystal structure packed along [101], in which Ag atoms are intercalated between the layers of hexagonally close-packed I atoms, and CO3 groups. Up to now, Cs3Pb2 (CO3)3I is the only other compound containing carbonate groups and iodide ions registered in the Inorganic Crystal Structure Database.
KW - Crystal structure
KW - Layered structure
KW - Silver carbonate iodide
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U2 - 10.1107/S2056989021006022
DO - 10.1107/S2056989021006022
M3 - Article
AN - SCOPUS:85113190541
VL - 77
SP - 734
EP - 738
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
SN - 2056-9890
ER -