Crystal structure of silver carbonate iodide Ag10(CO3)3I4

Ryoji Suzuki, Yuta Watanabe, Hisanori Yamane, Mamoru Kitaura, Kento Uchida, Yuta Matsushima

研究成果: Article査読

抄録

The title silver carbonate iodide, Ag10 (CO3)3I4, decasilver(I) tris(carbonate) tetraiodide, was recently reported as a precursor of the new superionic conductor Ag17 (CO3)3I11. Ag10 (CO3)3I4, was prepared by heating a stoichiometric powder mixture of AgI and Ag2CO3 at 430 K. A single-crystal suitable for X-ray diffraction analysis was obtained by slow cooling of a melt with an AgI-rich composition down from 453 K. Ag10 (CO3)3I4 exhibits a layered crystal structure packed along [101], in which Ag atoms are intercalated between the layers of hexagonally close-packed I atoms, and CO3 groups. Up to now, Cs3Pb2 (CO3)3I is the only other compound containing carbonate groups and iodide ions registered in the Inorganic Crystal Structure Database.

本文言語English
ページ(範囲)734-738
ページ数5
ジャーナルActa Crystallographica Section E: Crystallographic Communications
77
DOI
出版ステータスPublished - 2021 7 1

ASJC Scopus subject areas

  • 化学 (全般)
  • 材料科学(全般)
  • 凝縮系物理学

フィンガープリント

「Crystal structure of silver carbonate iodide Ag<sub>10</sub>(CO<sub>3</sub>)<sub>3</sub>I<sub>4</sub>」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル