Crystal structure and magnetic properties of Gd2([18]crown-6)2(OH)2 (CH3CN)2[Ni(dmit)2]4 complex having f- and π-spins

Sadafumi Nishihara, Tomoyuki Akutagawa, Tatsuo Hasegawa, Takayoshi Nakamura

研究成果: Article › 査読

35 被引用数 (Scopus)

抄録

Crystal structure and magnetic properties of Gd2([18]crown-6)2-(OH)2 (CH3CN)2[Ni(dmit)2]2 (dmit2- = 2-thioxo-1,3-dithiole-4,5-dithiolate) are reported. Gd3+ ions (S = 7/2) were introduced into the π-spin network of [Ni(dmit)2]- (S = 1/2) complex as a binuclear supramolecular cation, Gd2([18]crown)crown-6)2(OH)2 (CH3CN)2, in which two Gd([18]crown-6) units are bridged with two hydroxide ions. The weak antiferromagnetic interactions between Gd···Gd through hydroxide ions were observed, and [Ni(dmit)2]- formed isolated monomers and dimers in the crystal.

本文言語English
ページ（範囲）2480-2482
ページ数3
ジャーナルInorganic chemistry
巻42
号8
DOI
出版ステータスPublished - 2003 4 21
外部発表はい

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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フィンガープリント 「Crystal structure and magnetic properties of Gd<sub>2</sub>([18]crown-6)<sub>2</sub>(OH)<sub>2</sub> (CH<sub>3</sub>CN)<sub>2</sub>[Ni(dmit)<sub>2</sub>]<sub>4</sub> complex having f- and π-spins」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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