抄録
Crystal structure and magnetic properties of Gd2([18]crown-6)2-(OH)2 (CH3CN)2[Ni(dmit)2]2 (dmit2- = 2-thioxo-1,3-dithiole-4,5-dithiolate) are reported. Gd3+ ions (S = 7/2) were introduced into the π-spin network of [Ni(dmit)2]- (S = 1/2) complex as a binuclear supramolecular cation, Gd2([18]crown)crown-6)2(OH)2 (CH3CN)2, in which two Gd([18]crown-6) units are bridged with two hydroxide ions. The weak antiferromagnetic interactions between Gd···Gd through hydroxide ions were observed, and [Ni(dmit)2]- formed isolated monomers and dimers in the crystal.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 2480-2482 |
| ページ数 | 3 |
| ジャーナル | Inorganic chemistry |
| 巻 | 42 |
| 号 | 8 |
| DOI | |
| 出版ステータス | Published - 2003 4月 21 |
| 外部発表 | はい |
ASJC Scopus subject areas
- 物理化学および理論化学
- 無機化学