Crystal structure and electrical conductivity of [NH4+][18-crown-6][Ni(dmit)2]3

Tomoyuki Akutagawa, T. Nakamura, T. Inabe, A. E. Underhill

研究成果: Conference article査読

抄録

The [NH4+][Ni(dmit)2]3 complex, containing a macrocyclic molecule of 18-crown-6-ether (18C6), was obtained as [NH4+[18C6][Ni(dmit)2]3. This salt showed semiconducting behaviour with room temperature conductivity of 0.4 Scm-1. The crystal is composed of segregated non-uniform stack of Ni(dmit)2 and isolated ion-captured cavity of [NH4+][18C6]. The NH4+ ion was fully included in a cavity, and was tightly bounded through strong hydrogen bonds to the oxygen atoms of 18C6.

本文言語English
ページ(範囲)1861-1862
ページ数2
ジャーナルSynthetic Metals
86
1 -3 pt 3
DOI
出版ステータスPublished - 1997 1 1
外部発表はい
イベントProceedings of the 1996 International Conference on Science and Technology of Synthetic Metals, ICSM'96. Part 3 (of 3) - Snowbird, UT, USA
継続期間: 1996 7 281996 8 2

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • 材料力学
  • 機械工学
  • 金属および合金
  • 材料化学

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「Crystal structure and electrical conductivity of [NH<sub>4</sub><sup>+</sup>][18-crown-6][Ni(dmit)<sub>2</sub>]<sub>3</sub>」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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