Crystal design of cation-radical salts based on the supramolecular self-organizing arrangement of mellitate anions

T. Inabe, N. Kobayashi, T. Naito

研究成果: Conference article査読

5 被引用数 (Scopus)

抄録

Mellitate anions form hydrogen-bonding infinite networks in the salts with pyridinium cations. The network pattern depends on the number of deprotonation (n) from the mellitic acid; for n = 3, triangular hydrogen-bond units form a two-dimensional sheet, while for n = 2, dual hydrogen-bond units induce one-dimensional belts or two-dimensional grids. These self-organizing properties have been utilized for the crystal design of the TTF-type radical cation salts. Crystallization with TMTTF gave two kinds of crystals. One of the radical cation salt crystals consists of a channel network of the anions and one-dimensional columns of TMTTF in the channels. In the other TMTTF salt, the anions with n = 1 form a two-dimensional sheet with methanol molecules. The TMTTF radicals are packed between the sheets with their molecular planes parallel to the anion planes.

本文言語English
ページ(範囲)449-453
ページ数5
ジャーナルJournal De Physique. IV : JP
114
DOI
出版ステータスPublished - 2004 12 1
イベントISCOM 2003: 5th International Symposium on Crystalline Organic Metals, Superconductors and Ferromagnets - Port-Bourgenay, France
継続期間: 2003 9 212003 9 26

ASJC Scopus subject areas

  • 物理学および天文学(全般)

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