Coordinatively unsaturated Ru(II) species Ru(xantsil)(CO): A new active catalyst for oligomerization/deoligomerization of HSiMe2SiMe3 [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]. Isolation of a stabilized form of the silyl(silylene) intermediates

Jim Josephus G. Minglana, Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino

研究成果: Article

21 引用 (Scopus)

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Ru(xantsil)(CO)(η6-C6H5CH3) (1) was found to be a catalyst for the oligomerization/deoligomerization of HSiMe2SiMe3 to give H(SiMe2)nMe (n = 1-8). A possible mechanism involving a silyl(silylene) intermediate was strongly supported by the isolation of its stabilized form, i.e., alkoxy-bridged bis(silylene) complex which was characterized by X-ray crystal structure analysis.

元の言語English
ページ(範囲)406-407
ページ数2
ジャーナルChemistry Letters
発行部数3
DOI
出版物ステータスPublished - 2002 3 5

ASJC Scopus subject areas

  • Chemistry(all)

フィンガープリント Coordinatively unsaturated Ru(II) species Ru(xantsil)(CO): A new active catalyst for oligomerization/deoligomerization of HSiMe<sub>2</sub>SiMe<sub>3</sub> [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]. Isolation of a stabilized form of the silyl(silylene) intermediates' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

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