Convenient One-Pot Synthesis of Vinylic Sulfides from Thioalkynes via a Catalytic Hydroboration-Coupling Sequence

Ilya D. Gridnev, Norio Miyaura, Akira Suzuki

研究成果: Article査読

56 被引用数 (Scopus)

抄録

A variety of vinylic sulfides are stereospecifically synthesized by the catalytic hydroboration of thioacetylenes with catecholborane followed by cross-coupling of the resulting boron derivatives with organic halides. The use of the same palladium catalyst for both stages allows the whole transformation to be carried out in one flask. The synthetic utility of the method is demonstrated by the transformation of vinylic sulfides into diene, indole, and naphtho[b]furan derivatives.

本文言語English
ページ(範囲)5351-5354
ページ数4
ジャーナルJournal of Organic Chemistry
58
20
DOI
出版ステータスPublished - 1993 1 1
外部発表はい

ASJC Scopus subject areas

  • Organic Chemistry

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