Controllable bandgap of Cu2ZnSn(S,Se)4 thin films via simultaneous supercritical fluid chalcogenization

研究成果: Article査読

6 被引用数 (Scopus)

抄録

Supercritical ethanol (scEtOH), with its high solubility and reducibility, can be used as a medium to fabricate chalcogenide semiconductors from stable solid chalcogen sources. We fabricated Cu2ZnSn(S,Se)4 films via chalcogenization of Cu-Zn-Sn oxide precursor films using scEtOH to dissolve SeO2 and elemental sulfur (S8). The S/Se molar ratio and the bandgap of Cu2ZnSn(S,Se)4 films were controlled by changing the input ratio of selenium source (SeO2) to sulfur source (S8). Analysis indicated that high-density atomic chalcogens are the dominant reactive species. This process may contribute to the development of non-vacuum fabrication methods for chalcogenide-semiconductor solar cells.

本文言語English
ページ(範囲)21201
ページ数1
ジャーナルApplied Physics Express
8
2
DOI
出版ステータスPublished - 2015 2 1

ASJC Scopus subject areas

  • 工学(全般)
  • 物理学および天文学(全般)

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