Control over the Aspect Ratio of Supramolecular Nanosheets by Molecular Design

Norihiko Sasaki, Jennifer Yuan, Tomoya Fukui, Masayuki Takeuchi, Kazunori Sugiyasu

研究成果: Article査読

11 被引用数 (Scopus)

抄録

Recent developments in kinetically controlled supramolecular polymerization permit control of the size (i.e., length and area) of self-assembled nanostructures. However, control of molecular self-assembly at a level comparable with organic synthetic chemistry and the achievement of structural complexity at a hierarchy larger than the molecular level remain challenging. This study focuses on controlling the aspect ratio of supramolecular nanosheets. A systematic understanding of the relationship between the monomer structure and the self-assembly energy landscape has derived a new monomer capable of forming supramolecular nanosheets. With this monomer in hand, the aspect ratio of a supramolecular nanosheet is demonstrated that it can be controlled by modulating intermolecular interactions in two dimensions.

本文言語English
ページ(範囲)7840-7846
ページ数7
ジャーナルChemistry - A European Journal
26
35
DOI
出版ステータスPublished - 2020 6月 23
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 有機化学

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