@article{59342aea30fe431b833d384d2800ceeb,
title = "Consecutive O−S/N−S Bond Cleavage in Gold-Catalyzed Rearrangement Reactions of Alkynyl N-Sulfinylimines",
abstract = "Gold-catalyzed reactions of alkynyl N-sulfinylimines were used to produce the corresponding 2H-azirines possessing sulfenyl and acyl groups at the 3-position of the azirine ring in good to excellent yields. These reactions involved internal transfer of the sulfinyl oxygen atom to form a thiooxime intermediate tethered to an α-oxo gold carbene moiety. Subsequent insertion of the carbene into the N−S bond resulted in ring construction.",
keywords = "alkynes, carbenes, gold, heterocycles, rearrangement",
author = "Hiroki Tashiro and Masahiro Terada and Itaru Nakamura",
note = "Funding Information: This research was supported by JSPS KAKENHI Grant Number JP20H02731, Grant‐in‐Aid for Scientific Research (B). We thank Prof. Ilya D. Gridnev for a valuable discussion on DFT calculations. Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",
year = "2021",
month = may,
day = "25",
doi = "10.1002/anie.202100207",
language = "English",
volume = "60",
pages = "12248--12252",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "22",
}