Verknüpfung von (TeO6)6-und (TeO6)3(NiO6)3-sechsringen durch TeNiO9-oktaederdoppel in Pb3Ni4,5Te2,5O15

B. Wedel, K. Sugiyama, Hk Müller-Buschbaum

研究成果: Article査読

9 被引用数 (Scopus)

抄録

Single crystals of Pb3Ni4,5Te2,5O15 have been prepared by heating pellets of mixtures of PbO, TeO2 and nickel hydroxide carbonate to 730 °C in air. X-ray investigations led to hexagonal symmetry, space group D66-P6322, lattice constants a = 10.2589(1), c = 13.554(5), Z = 4. Typical features of the crystal structure are face sharing TeNiO9 octahedra doubles and planes of connected (TeO6)6 and (TeO6)3(NiO6)3 hexagons. The one-sided coordination of lead by oxygen is complemented by the lone pair of electrons. The lone pair positions are estimated by calculations of the Coulomb terms of lattice energy.

寄稿の翻訳タイトルConnection of (TeO6)6 and (TeO6)3(NiO6)3 hexagons by TeNiO9 octahedra double in Pb3Ni4,5Te2,5O15
本文言語German
ページ(範囲)527-531
ページ数5
ジャーナルZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
53
5-6
DOI
出版ステータスPublished - 1998

ASJC Scopus subject areas

  • 化学 (全般)

フィンガープリント

「Verknüpfung von (TeO<sub>6</sub>)<sub>6</sub>-und (TeO<sub>6</sub>)<sub>3</sub>(NiO<sub>6</sub>)<sub>3</sub>-sechsringen durch TeNiO<sub>9</sub>-oktaederdoppel in Pb<sub>3</sub>Ni<sub>4,5</sub>Te<sub>2,5</sub>O<sub>15</sub>」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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