Conducting single-molecule magnet materials

Goulven Cosquer, Yongbing Shen, Manuel Almeida, Masahiro Yamashita

研究成果: Review article

16 引用 (Scopus)

抜粋

Multifunctional molecular materials exhibiting electrical conductivity and single-molecule magnet (SMM) behaviour are particularly attractive for electronic devices and related applications owing to the interaction between electronic conduction and magnetization of unimolecular units. The preparation of such materials remains a challenge that has been pursued by a bi-component approach of combination of SMM cationic (or anionic) units with conducting networks made of partially oxidized (or reduced) donor (or acceptor) molecules. The present status of the research concerning the preparation of molecular materials exhibiting SMM behaviour and electrical conductivity is reviewed, describing the few molecular compounds where both SMM properties and electrical conductivity have been observed. The evolution of this research field through the years is discussed. The first reported compounds are semiconductors in spite being able to present relatively high electrical conductivity, and the SMM behaviour is observed at low temperatures where the electrical conductivity of the materials is similar to that of an insulator. During the recent years, a breakthrough has been achieved with the coexistence of high electrical conductivity and SMM behaviour in a molecular compound at the same temperature range, but so far without evidence of a synergy between these properties. The combination of high electrical conductivity with SMM behaviour requires not only SMM units but also the regular and as far as possible uniform packing of partially oxidized molecules, which are able to provide a conducting network.

元の言語English
ページ(範囲)7616-7627
ページ数12
ジャーナルDalton Transactions
47
発行部数23
DOI
出版物ステータスPublished - 2018 1 1

ASJC Scopus subject areas

  • Inorganic Chemistry

フィンガープリント Conducting single-molecule magnet materials' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用

    Cosquer, G., Shen, Y., Almeida, M., & Yamashita, M. (2018). Conducting single-molecule magnet materials. Dalton Transactions, 47(23), 7616-7627. https://doi.org/10.1039/c8dt01015c