Conducting complexes of TTF and TSF derivatives fused with selenium-containing five-membered rings

T. Jigami, K. Takimiya, Y. Aso, T. Otsubo

研究成果: Conference article査読

9 被引用数 (Scopus)

抄録

Electrocrystallization of bis(ethyleneseleno)-tetrathiafulvalene (BES-TTF) and -tetraselenafulvalene (BES-TSF) gave a variety of radical cation salts which had high room-temperature conductivities (60-280 S cm-1) and displayed a metal-to-semiconductor (insulator) transition at low temperature. Among them, however, the ClO4- and AsF6- salts of BES-TSF remained highly conducting even at cryogenic temperature. An X-ray crystallographic analysis of (BES-TTF)2SbF6, revealed that the complex carries a considerably two-dimensional interactive electronic structure.

本文言語English
ページ(範囲)1714-1715
ページ数2
ジャーナルSynthetic Metals
102
1-3
DOI
出版ステータスPublished - 1999 6月
外部発表はい
イベントProceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier
継続期間: 1998 7月 121998 7月 18

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • 材料力学
  • 機械工学
  • 金属および合金
  • 材料化学

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