Conclusive determination of the absolute configuration of chiral C 60-fullerene cis-3 bisadducts by X-ray crystallography and circular dichroism

Shunsuke Kuwahara, Kazuhiro Obata, Kazuhiro Yoshida, Takatoshi Matsumoto, Nobuyuki Harada, Nobuhiro Yasuda, Yoshiki Ozawa, Koshiro Toriumi

研究成果: Article査読

19 被引用数 (Scopus)

抄録

Ultrathin red plate crystals of a chiral C60-fullerene cis-3 bisadduct were subjected to X-ray crystallographic analysis to finally determine the absolute configuration of such an adduct conclusively (see picture; C gray, O red, H blue). A comparison of its circular-dichroism spectrum with those of similar compounds suggested that the absolute configurations reported for some compounds may require revision (Figure Presented).

本文言語English
ページ(範囲)2262-2265
ページ数4
ジャーナルAngewandte Chemie - International Edition
44
15
DOI
出版ステータスPublished - 2005 4月 8

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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