Complexation of lanthanide ions with polymerizable macrocyclic calixarene derivatives for polymer optical device applications

Rahmat Hidayat, Okihiro Sugihara, Masaaki Tsuchimori, Manabu Kagami, Tadatomi Nishikubo, Toshikuni Kaino

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Incorporation of lanthanide ions in polymerizable macrocylic molecules, such as calixarene and calix- resorcinarene monomers, has been studied by 1H NMR and fluorescence spectroscopies. The complexation formation through non-ionic coordination bond with the upper rim oxygen of resorcinarene monomers was clarified by the observation of dipolar shift in NMR spectrum. The complexation results in broadening of fluorescence peak and elongation of the fluorescence decay, which are attributed to increasing anisotropy of ligand field due to this complexation.

本文言語English
ページ(範囲)91-94
ページ数4
ジャーナルNonlinear Optics Quantum Optics
34
1-4 SPEC. ISS.
出版ステータスPublished - 2005 12 19

ASJC Scopus subject areas

  • Statistical and Nonlinear Physics
  • Electronic, Optical and Magnetic Materials
  • Computer Science(all)
  • Atomic and Molecular Physics, and Optics
  • Instrumentation

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