Complete infrared spectroscopic characterization of phenol-borane- trimethylamine dihydrogen-bonded complex in the gas phase

G. Naresh Patwari, Asuka Fujii, Naohiko Mikami

研究成果: Article査読

20 被引用数 (Scopus)

抄録

In the paper we report the first observation of the vibrational spectrum in the B-H stretching region in the gas phase for a dihydrogen bonded complex. The appearance of three transitions for the B-H stretching modes of a (di)hydrogen-bonded complex involving borane-trimethylamine indicates the lowering of the symmetry on the BH3 group upon interaction with phenol. Further, the shift in the O-H stretching frequency indicates that phenol is hydrogen bonded to borane-trimethylamine. The two sets of the present data establish, unequivocally, the formation of O-H⋯H-B dihydrogen-bonded complex between phenol and borane-trimethylamine.

本文言語English
論文番号241103
ジャーナルJournal of Chemical Physics
124
24
DOI
出版ステータスPublished - 2006

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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