Combined proline-surfactant organocatalyst for the highly diastereo- and enantioselective aqueous direct cross-aldol reaction of aldehydes

Yujiro Hayashi, Seiji Aratake, Tsubasa Okano, Junichi Takahashi, Tatsunobu Sumiya, Mitsuru Shoji

研究成果: Article査読

278 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Why not combine the two? The asymmetric direct aldol reaction of two different aldehydes was catalyzed by a combined proline-surfactant organic catalyst in the presence of water. A stable emulsion was formed in the reaction mixture, and the aldols were obtained with excellent diastereo- and enantioselectivities (see scheme).

本文言語English
ページ(範囲)5527-5529
ページ数3
ジャーナルAngewandte Chemie - International Edition
45
33
DOI
出版ステータスPublished - 2006 8 18
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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