Chromium-Salen Complex/Nitroxyl Radical Cooperative Catalysis: A Combination for Aerobic Intramolecular Dearomative Coupling of Phenols

研究成果: Article査読

抄録

We describe an aerobic intramolecular dearomative coupling reaction of tethered phenols using a catalytic system consisting of a chromium-salen (Cr-salen) complex combined with a nitroxyl radical. This novel catalytic system enables formation of various spirocyclic dienone products including those unable to be accessed by previously reported methods efficiently under mild reaction conditions.

本文言語English
ページ(範囲)6952-6968
ページ数17
ジャーナルJournal of Organic Chemistry
86
9
DOI
出版ステータスPublished - 2021 5 7

ASJC Scopus subject areas

  • 有機化学

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