Chromic and fluorescence response system based on the dihydrophenanthroline-bipyridine skeleton: dynamic redox behavior and metal binding properties

Takanori Suzuki, Ryuuichi Tamaki, Eisuke Ohta, Takashi Takeda, Hidetoshi Kawai, Kenshu Fujiwara, Masako Kato

研究成果: Article査読

12 被引用数 (Scopus)

抄録

The spiro-acridan/acridinium-based dynamic redox pair (1/22+) transduces the electrochemical input into UV-vis and fluorescence spectra, whereas the 2,2′-bipyridine units in 1 works as a bidentate ligand for metal ions. X-ray structural analyses of this redox pair and the corresponding Zn-complexes [1-ZnI2/22+-Zn2+(OTf-)4] demonstrate drastic structural changes upon electron-transfer, thus metal binding properties are modified by redox reactions.

本文言語English
ページ(範囲)3823-3827
ページ数5
ジャーナルTetrahedron Letters
48
22
DOI
出版ステータスPublished - 2007 5 28
外部発表はい

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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