Chloro and hydroxo forms of a boron(III) subtriazaporphyrin macrocycle

Jay R. Stork, Jeffrey J. Brewer, Takamitsu Fukuda, Jeffrey P. Fitzgerald, Gordon T. Yee, Alexander Y. Nazarenko, Nagao Kobayashi, William S. Durfee

研究成果: Article

39 引用 (Scopus)

抜粋

cis-3,4-Dicyano-3-hexene undergoes cyclotrimerization with BCl3 to form the new subtriazaporphyrin chloro[hexaethylsubtriazaporphyrinato] boron(III). The hydroxo derivative of this macrocycle has also been made, and the X-ray crystal structure of the hydroxy form was determined. Electronic absorption and magnetic circular dichroism spectra of the hydroxo monomer species were interpreted using time-dependent density functional theory calculations.

元の言語English
ページ(範囲)6148-6151
ページ数4
ジャーナルInorganic chemistry
45
発行部数16
DOI
出版物ステータスPublished - 2006 8 7

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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  • これを引用

    Stork, J. R., Brewer, J. J., Fukuda, T., Fitzgerald, J. P., Yee, G. T., Nazarenko, A. Y., Kobayashi, N., & Durfee, W. S. (2006). Chloro and hydroxo forms of a boron(III) subtriazaporphyrin macrocycle. Inorganic chemistry, 45(16), 6148-6151. https://doi.org/10.1021/ic051093u