Chemical bond cleavage induced by electron heating Gas emission behavior of titanium-metalloid compounds (titanium nitride and oxide) in a microwave field

Jun Fukushima, Keiichiro Kashimura, Motoyasu Sato

研究成果: Article査読

11 被引用数 (Scopus)

抄録

Gas emissions from titanium-metalloid compounds (titanium nitride and oxide) have been investigated to understand the effects of a microwave field on chemical reactions. We employed a high vacuum system (PO2 =10 -6 Pa) to observe in situ reductions. For titanium oxides, H-field heating significantly differed from conventional one in terms of oxygen emissions. For titanium nitride, the emissions were also induced by microwave heating. These tendencies were observed at temperatures above 1000 °C. A quantum chemical interpretation is provided to explain the emissions of the gases, and the experimental data is in good agreement with results predicted using the electronic energy band structure.

本文言語English
ページ(範囲)178-183
ページ数6
ジャーナルMaterials Chemistry and Physics
131
1-2
DOI
出版ステータスPublished - 2011 12 15
外部発表はい

ASJC Scopus subject areas

  • 材料科学(全般)
  • 凝縮系物理学

フィンガープリント

「Chemical bond cleavage induced by electron heating Gas emission behavior of titanium-metalloid compounds (titanium nitride and oxide) in a microwave field」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル