Charge-transfer dynamics in cyano-bridged MA-Fe system (M A = Mn, Fe, and Co)

Hayato Kamioka, Yutaka Moritomo, Wataru Kosaka, Shinichi Ohkoshi

研究成果: Article査読

8 被引用数 (Scopus)

抄録

Charge-transfer (CT) dynamics has been investigated for Prussian blue-type MA-Fe cyanides (MA = Mn, Fe, and Co) grown in hydrophilic cavities of a Nafion 117 film. In all the compounds, we observed the suppression of the original CT absorption between neighboring transition metals. We found that the spectral profile of the slow component for the Fe compound is similar to that for the Co compound, reflecting the photo created d6 state at the MA site.

本文言語English
論文番号093710
ジャーナルjournal of the physical society of japan
77
9
DOI
出版ステータスPublished - 2008 9
外部発表はい

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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