Cationic cobalt-catalyzed [1,3]-rearrangement of N-alkoxycarbonyloxyanilines

Itaru Nakamura, Mao Owada, Takeru Jo, Masahiro Terada

研究成果: Article査読

1 被引用数 (Scopus)

抄録

A cationic cobalt catalyst efficiently promoted the reaction of N-alkoxycarbonyloxyanilines at 30 °C, affording the corresponding ortho-aminophenols in good to high yields. As reported previously, our mechanistic studies including oxygen-18 labelling experiments indicate that the rearrangement of the alkoxycarbonyloxy group proceeds in [1,3]-manner. In this article, we discuss the overall picture of the cobalt-catalysed [1,3]-rearrangement reaction including details of the reaction conditions and substrate scope.

本文言語English
ページ(範囲)1972-1979
ページ数8
ジャーナルBeilstein Journal of Organic Chemistry
14
DOI
出版ステータスPublished - 2018 7月 31

ASJC Scopus subject areas

  • 有機化学

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