Catalytic enantioselective carbon-carbon bond forming reactions of masked acyl cyanides

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Protected hydroxyl malononitriles, known as masked acyl cyanide (MAC) reagents are one of the most useful umpolung synthons to function as carbon monoxide equivalents with both nucleophilic and electorophilic reactivity. This dual reactivity, only characteristic in a few acyl anion equivalents, enables MAC reagents to afford a series of structurally diverse products by a one-carbon homologation under mild conditions. This review highlights the utility of MAC reagents in catalytic enantioselective carbon-carbon bond forming reactions that have been reported recently.

本文言語English
ページ(範囲)255-256
ページ数2
ジャーナルYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
76
3
DOI
出版ステータスPublished - 2018
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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