Bis-silyl Chelate Ligand Precursor XantsilH2 and Some Ruthenium Xantsil Complexes

H. Tobita

研究成果: Chapter

抜粋

The ligand precursor xantsilH2 was prepared by selective dilithiation at the 4,5-positions of 9,9-dimethylxanthene with 2 equiv of n-BuLi/TMEDA followed by reaction with chlorodimethylsilane. Heating a solution of xantsilH2 with 0.4M equiv of Ru3(CO)12 in toluene to 120°C for 90min provided cis-Ru(xantsil)(CO)4. Three carbonyl ligands in cis-Ru(xantsil)(CO)4 can be replaced by a η6-toluene ligand to give Ru(xantsil)(CO)(η6-C6H5Me) in high yield. Substitution of the η6-toluene ligand with PCy3 afforded Ru(xantsil)(CO)(PCy3), which serves as a unique, high-performance catalyst.

元の言語English
ホスト出版物のタイトルEfficient Methods for Preparing Silicon Compounds
出版者Elsevier Inc.
ページ375-380
ページ数6
ISBN(電子版)9780128035689
ISBN(印刷物)9780128035306
DOI
出版物ステータスPublished - 2016 5 31

ASJC Scopus subject areas

  • Chemistry(all)

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  • これを引用

    Tobita, H. (2016). Bis-silyl Chelate Ligand Precursor XantsilH2 and Some Ruthenium Xantsil Complexes. : Efficient Methods for Preparing Silicon Compounds (pp. 375-380). Elsevier Inc.. https://doi.org/10.1016/B978-0-12-803530-6.00027-5