Binaphthol-Titanium Complex-Catalyzed Fluoral-Ene Reaction with Vinyl Sulfides for Asymmetric Synthesis of Diastereomeric α-Trifluoromethyl-β-methyl Carbinols: Diastereomer Switch of Antiferroelectric or Ferroelectric Properties of Diastereomeric Liquid-Crystalline Systems

Koichi Mikami, Tomoko Yajima, Nasakul Siree, Masahiro Terada, Yoshiichi Suzuki, Ichiro Kobayashi

研究成果: Article査読

25 被引用数 (Scopus)

抄録

We synthesized a new type of antiferroelectric and ferroelectric liquid-crystalline molecules with double stereogenic centers based on the binaphthol-titanium complex-catalyzed fluoralene reaction with vinyl sulfides. Furthermore, we experimentally showed the importance of the diastereomer effect for the appearance of the antiferroelectric SmCA* phase.

本文言語English
ページ(範囲)837-838
ページ数2
ジャーナルSynlett
1996
9
DOI
出版ステータスPublished - 1996
外部発表はい

ASJC Scopus subject areas

  • Organic Chemistry

フィンガープリント 「Binaphthol-Titanium Complex-Catalyzed Fluoral-Ene Reaction with Vinyl Sulfides for Asymmetric Synthesis of Diastereomeric α-Trifluoromethyl-β-methyl Carbinols: Diastereomer Switch of Antiferroelectric or Ferroelectric Properties of Diastereomeric Liquid-Crystalline Systems」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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