Axially chiral guanidine as enantioselective base catalyst for 1,4-addition reaction of 1,3-dicarbonyl compounds with conjugated nitroalkenes

Masahiro Terada, Hitoshi Ube, Yusuke Yaguchi

研究成果: Article査読

230 被引用数 (Scopus)

抄録

A new strategy for designing chiral guanidine molecules is presented, which features the introduction of an axially chiral binaphthyl backbone. The axially chiral guanidine catalysts thus developed facilitated the highly enantioselective 1,4-addition reaction of 1,3-dicarbonyl compounds with a broad range of conjugated nitroalkenes and showed extremely high catalytic activity.

本文言語English
ページ(範囲)1454-1455
ページ数2
ジャーナルJournal of the American Chemical Society
128
5
DOI
出版ステータスPublished - 2006 2 8

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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