Atomic observation of catalysis-induced nanopore coarsening of nanoporous gold

Takeshi Fujita, Tomoharu Tokunaga, Ling Zhang, Dongwei Li, Luyang Chen, Shigeo Arai, Yuta Yamamoto, Akihiko Hirata, Nobuo Tanaka, Yi Ding, Mingwei Chen

研究成果: Article査読

97 被引用数 (Scopus)

抄録

Dealloyed nanoporous metals have attracted much attention because of their excellent catalytic activities toward various chemical reactions. Nevertheless, coarsening mechanisms in these catalysts have not been experimentally studied. Here, we report in situ atomic-scale observations of the structural evolution of nanoporous gold during catalytic CO oxidation. The catalysis-induced nanopore coarsening is associated with the rapid diffusion of gold atoms at chemically active surface steps and the surface segregation of residual Ag atoms, both of which are stimulated by the chemical reaction. Our observations provide the first direct evidence that planar defects hinder nanopore coarsening, suggesting a new strategy for developing structurally stable and highly active heterogeneous catalysts.

本文言語English
ページ(範囲)1172-1177
ページ数6
ジャーナルNano Letters
14
3
DOI
出版ステータスPublished - 2014 3月 12

ASJC Scopus subject areas

  • バイオエンジニアリング
  • 化学 (全般)
  • 材料科学(全般)
  • 凝縮系物理学
  • 機械工学

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