Asymmetric synthesis with a chiral catalyst generated from asymmetric autocatalysis

Itaru Sato, Hiroki Urabe, Shinji Ishii, Shigehisa Tanji, Kenso Soai

研究成果: Article

17 引用 (Scopus)

抜粋

Equation Presented A new and efficient one-pot system of asymmetric catalysis is presented in which a chiral catalyst (5-pyrimidyl alkanol) self-improves its ee by asymmetric autocatalysis and then acts as a highly enantioselective chiral catalyst for other asymmetric synthesis (addition of dialkylzincs to aldehydes) to provide products (sec-alcohols) with very high ee (up to 99%).

元の言語English
ページ(範囲)3851-3853
ページ数3
ジャーナルOrganic letters
3
発行部数24
DOI
出版物ステータスPublished - 2001 11 29

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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