抄録
Asymmetric epoxidation of α-substituted acroleins with hydrogen peroxide has been catalyzed by diphenylprolinol diphenylmethylsilyl ether to afford α-substituted-β,β-unsubstituted-α,β-epoxy aldehyde with excellent enantioselectivity and the generation of a chiral quaternary carbon center. The method was applied to a short synthesis of (R)-methyl palmoxirate.
本文言語 | English |
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ページ(範囲) | 5434-5437 |
ページ数 | 4 |
ジャーナル | Organic letters |
巻 | 12 |
号 | 23 |
DOI | |
出版ステータス | Published - 2010 12月 3 |
外部発表 | はい |
ASJC Scopus subject areas
- 生化学
- 物理化学および理論化学
- 有機化学