抄録
Asymmetric epoxidation of α-substituted acroleins with hydrogen peroxide has been catalyzed by diphenylprolinol diphenylmethylsilyl ether to afford α-substituted-β,β-unsubstituted-α,β-epoxy aldehyde with excellent enantioselectivity and the generation of a chiral quaternary carbon center. The method was applied to a short synthesis of (R)-methyl palmoxirate.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 5434-5437 |
| ページ数 | 4 |
| ジャーナル | Organic letters |
| 巻 | 12 |
| 号 | 23 |
| DOI | |
| 出版ステータス | Published - 2010 12 3 |
| 外部発表 | はい |
ASJC Scopus subject areas
- 生化学
- 物理化学および理論化学
- 有機化学