Asymmetric, catalytic, and direct self-aldol reaction of acetaldehyde catalyzed by diarylprolinol

Yujiro Hayashi, Sampak Samanta, Takahiko Itoh, Hayato Ishikawa

研究成果: Article査読

64 被引用数 (Scopus)

抄録

(Chemical Equation Presented) An asymmetric, catalytic, and direct self-aldol reaction of acetaldehyde was catalyzed by diarylprolinol in NMP, affording the trimer acetal, which was generated by the reaction of the self-aldol product with another acetaldehyde molecule in a moderate yield with good enantioselectivity. Acetal is the synthetic equivalent of the self-aldol product, which can be converted into other synthetically useful compounds in one pot without compromising the enantioselectivity.

本文言語English
ページ(範囲)5581-5583
ページ数3
ジャーナルOrganic letters
10
24
DOI
出版ステータスPublished - 2008
外部発表はい

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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