Asymmetric activation of chiral BINOL-zirconium catalysts: Effect of a product-like activator

Thorsten Volk, Toshinobu Korenaga, Satoru Matsukawa, Masahiro Terada, Koichi Mikami

研究成果: Article査読

15 被引用数 (Scopus)

抄録

The asymmetric activation of binaphthol (BINOL)-zirconium catalysts is described on the enantioselective allylation of benzaldehyde with allyltin reagents. This model reaction has been used with the intention of establishing a protocol for a zirconium-based catalyst system, to be followed by structural studies. Initial results are reported that characterise a number of interesting features, namely the influence of an induction period and a high level of asymmetric activation obtained after addition of a product-like activator.

本文言語English
ページ(範囲)717-721
ページ数5
ジャーナルChirality
10
7
DOI
出版ステータスPublished - 1998 1 1
外部発表はい

ASJC Scopus subject areas

  • Analytical Chemistry
  • Catalysis
  • Pharmacology
  • Drug Discovery
  • Spectroscopy
  • Organic Chemistry

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