Anthryl-substituted 3-silylene-2-silaaziridine obtained by isomerization of disilacyclopropanimine: An exocyclic silene showing a distinct intramolecular charge transfer transition

Takeaki Iwamoto, Nobuyoshi Ohnishi, Naohiko Akasaka, Koichi Ohno, Shintaro Ishida

研究成果: Article査読

23 被引用数 (Scopus)

抄録

An anthryl-substituted exocyclic silene, 3-silylene-2-silaaziridine, was synthesized by isomerization of the corresponding disilacyclopropanimine. The UV-vis spectrum of the silene shows a distinct intramolecular charge transfer (ICT) transition from the π orbital of the Si=C double bond to the π* orbital of the anthryl moiety. The relatively high-lying π(Si=C) orbital of the 3-silylene-2-silaaziridine moiety and the low-lying π* orbital of the anthryl group would be responsible for the distinct ICT band.

本文言語English
ページ(範囲)10606-10609
ページ数4
ジャーナルJournal of the American Chemical Society
135
29
DOI
出版ステータスPublished - 2013 7 24

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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