Anion Recognition at the Solid/Liquid Interface as Studied by Second Harmonic Generation Spectroscopy

Akira Yamaguchi; Ryo Kato; Seiichi Nishizawa; Norio Teramae

doi:10.1246/cl.2003.798

Anion Recognition at the Solid/Liquid Interface as Studied by Second Harmonic Generation Spectroscopy

Akira Yamaguchi, Ryo Kato, Seiichi Nishizawa, Norio Teramae

理学研究科・化学専攻

研究成果: Article › 査読

5 被引用数 (Scopus)

抄録

A self-assembled monolayer of thiourea-based anion receptor was formed at a gold surface, and its affinity with monovalent inorganic anions (MeCO ₂^-, H₂PO₄^-, Cl ^-) in acetonitrile solution was examined by second harmonic generation spectroscopy. The estimated adsorption coefficients of anions at the monolayer reveal specific binding selectivity compared with the selectivity found in a bulk acetonitrile phase.

本文言語	English
ページ（範囲）	798-799
ページ数	2
ジャーナル	Chemistry Letters
巻	32
号	9
DOI	https://doi.org/10.1246/cl.2003.798
出版ステータス	Published - 2003 9 5

ASJC Scopus subject areas

Chemistry(all)

文献へのアクセス

10.1246/cl.2003.798

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引用スタイル

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abstract = "A self-assembled monolayer of thiourea-based anion receptor was formed at a gold surface, and its affinity with monovalent inorganic anions (MeCO 2-, H2PO4-, Cl -) in acetonitrile solution was examined by second harmonic generation spectroscopy. The estimated adsorption coefficients of anions at the monolayer reveal specific binding selectivity compared with the selectivity found in a bulk acetonitrile phase.",

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AB - A self-assembled monolayer of thiourea-based anion receptor was formed at a gold surface, and its affinity with monovalent inorganic anions (MeCO 2-, H2PO4-, Cl -) in acetonitrile solution was examined by second harmonic generation spectroscopy. The estimated adsorption coefficients of anions at the monolayer reveal specific binding selectivity compared with the selectivity found in a bulk acetonitrile phase.

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