Anion-driven structures and SMM behavior of dinuclear terbium and ytterbium complexes

Leena Mandal, Soumava Biswas, Goulven Cosquer, Yongbing Shen, Masahiro Yamashita

研究成果: Article査読

18 被引用数 (Scopus)

抄録

The work in this present investigation reports the syntheses, crystal structures and magnetic properties of five dinuclear lanthanide complexes having compositions [Tb2(HL)4(NO3)6] (1), [Tb2(HL)4Cl6]·2EtOH (2), [Yb2(HL)4(NO3)6] (3), [Yb2(HL)4Cl6]·2EtOH (4) and [Y2(HL)4(NO3)6] (5) with HL = 8-hydroxyquinaldine. It is evident from the crystal structures that the coordination number of trivalent lanthanide ions in compounds 1, 3 and 5 is nine, whereas that for compounds 2 and 4 is six. A dynamic magnetic study shows that both compounds 1 and 3 exhibit single-molecule-magnet (SMM) behavior while compounds 2 and 4 do not have any SMM property.

本文言語English
ページ(範囲)17493-17499
ページ数7
ジャーナルDalton Transactions
47
48
DOI
出版ステータスPublished - 2018

ASJC Scopus subject areas

  • 無機化学

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