An M12(L1)12(L2)12 cantellated tetrahedron: A case study on mixed-ligand self-assembly

Qing Fu Sun, Sota Sato, Makoto Fujita

    研究成果: Article査読

    89 被引用数 (Scopus)

    抄録

    In the self-assembly of PdII ions and two different, but similarly shaped, ligands (1 and 2), neither random mixing nor self-sorting of the two ligands into two unmixed structures was observed. Instead a mixed, yet sorted, Pd12(1)12(2)12 cantellated tetrahedron (and its pseudoisomer) was selectively formed, thus revealing a fine example of intramolecular selfsorting. A case study showed that a homothetic ratio of >2 is necessary to observe cantellated tetrahedra.

    本文言語English
    ページ(範囲)13510-13513
    ページ数4
    ジャーナルAngewandte Chemie - International Edition
    53
    49
    DOI
    出版ステータスPublished - 2014 10月 7

    ASJC Scopus subject areas

    • 触媒
    • 化学 (全般)

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