An electron-transfer ferromagnet with Tc = 107 K based on a three-dimensional [Ru2]2/TCNQ system

Natsuko Motokawa, Hitoshi Miyasaka, Masahiro Yamashita, Kim R. Dunbar

研究成果: Article査読

114 被引用数 (Scopus)

抄録

Electron-transfer makes a magnet: 2:1 assembly of [Ru2 II,IIL4] paddlewheel complexes and BDTA-TCNQ yielded a new structural type of electron-transfer system with a three-dimensional network structure which exhibits a long-range ferromagnetic transition at Tc = 107 K (see depicted χ vs T curve and inset view of structure along the a axis). L = m-fluorobenzoate, BTDA-TCNQ = bis(1,2,5-thiadiazolo) tetracyanoquinodimethane.

本文言語English
ページ(範囲)7760-7763
ページ数4
ジャーナルAngewandte Chemie - International Edition
47
40
DOI
出版ステータスPublished - 2008 9 22

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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