Ammoniated alkali fullerides (ND3)xNaA2C60: Ammonia specific effects and superconductivity

Serena Margadonna, Efstathios Aslanis, Kosmas Prassides

研究成果: Article査読

20 被引用数 (Scopus)

抄録

The crystal structure of the superconducting (ND3)xNaA2C60 (0.7 ≤ × ≤ 1, A= K, Rb) fullerides (Tc= 6-15 K) has been studied by synchrotron X-ray and neutron powder diffraction. It is face-centered cubic (fcc) to low temperatures with Na+-ND3 pairs residing in the octahedral interstices. These are disordered over the corners of two "interpenetrating" cubes with the Na+ ions and the N atoms displaced by ∼2.0 Å and ∼0.5 Å from the center of the site and statically disordered over the corners of the inner and outer cube, respectively. Close contacts between the D atoms of the ND3 molecules and electron rich 6:6 C-C bonds of neighboring C60 units provide the signature of weak N-D⋯π hydrogen-bonding interactions, which control the intermolecular packing in the crystal and may determine the unusual superconducting properties.

本文言語English
ページ(範囲)10146-10156
ページ数11
ジャーナルJournal of the American Chemical Society
124
34
DOI
出版ステータスPublished - 2002 8 28
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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