Activities of titanium ions in molten calcium chloride

Jianxun Song, Liwen Hu, Qiuyu Wang, Shuqiang Jiao, Komin Shu

研究成果: Conference contribution

抄録

The subchloride titanium was prepared by sponge titanium and titanium tetrachloride in the CaCl<inf>2</inf> at 1173 K. The species were detected are mainly titanium dichloride, and the average valent in the melt are 2.05. The accurate equilibrium constants were obtained for the reaction 3Ti<sup>2+</sup> = 2Ti<sup>3+</sup>+Ti after the accurate activities of titanium chloride were evaluated with emf method, and the observed deviations from ideal behavior are discussed.

本文言語English
ホスト出版物のタイトルTMS Annual Meeting
出版社Minerals, Metals and Materials Society
ページ541-544
ページ数4
2015-March
ISBN(印刷版)9781119073574
出版ステータスPublished - 2015
外部発表はい
イベント6th International Symposium on High-Temperature Metallurgical Processing - TMS 2015 144th Annual Meeting and Exhibition - Orlando, United States
継続期間: 2015 3 152015 3 19

Other

Other6th International Symposium on High-Temperature Metallurgical Processing - TMS 2015 144th Annual Meeting and Exhibition
国/地域United States
CityOrlando
Period15/3/1515/3/19

ASJC Scopus subject areas

  • 凝縮系物理学
  • 材料力学
  • 金属および合金

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