Activation of a cyclobutanone carbon-carbon bond over an aldehyde carbon-hydrogen bond in the rhodium-catalyzed decarbonylation

Takanori Matsuda; Masanori Shigeno; Masahiro Murakami

doi:10.1246/cl.2006.288

Activation of a cyclobutanone carbon-carbon bond over an aldehyde carbon-hydrogen bond in the rhodium-catalyzed decarbonylation

Takanori Matsuda, Masanori Shigeno, Masahiro Murakami

研究成果: Article › 査読

34 被引用数 (Scopus)

抄録

A rhodium(I)-N-heterocyclic carbene complex achieved a high-yield decarbonylation reaction of cyclobutanones to selectively afford cyclopropanes. With this catalyst, a cyclobutanone having an aldehyde moiety underwent chemoselective decarbonylation of the ketonic carbonyl group with the aldehydic carbonyl group left intact.

本文言語	English
ページ（範囲）	288-289
ページ数	2
ジャーナル	Chemistry Letters
巻	35
号	3
DOI	https://doi.org/10.1246/cl.2006.288
出版ステータス	Published - 2006 3月 5
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

文献へのアクセス

10.1246/cl.2006.288

他のファイルとリンク

フィンガープリント

「Activation of a cyclobutanone carbon-carbon bond over an aldehyde carbon-hydrogen bond in the rhodium-catalyzed decarbonylation」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

@article{37d6c2ba1e1e490dbad3255958fd8214,

title = "Activation of a cyclobutanone carbon-carbon bond over an aldehyde carbon-hydrogen bond in the rhodium-catalyzed decarbonylation",

abstract = "A rhodium(I)-N-heterocyclic carbene complex achieved a high-yield decarbonylation reaction of cyclobutanones to selectively afford cyclopropanes. With this catalyst, a cyclobutanone having an aldehyde moiety underwent chemoselective decarbonylation of the ketonic carbonyl group with the aldehydic carbonyl group left intact.",

author = "Takanori Matsuda and Masanori Shigeno and Masahiro Murakami",

year = "2006",

month = mar,

day = "5",

doi = "10.1246/cl.2006.288",

language = "English",

volume = "35",

pages = "288--289",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "3",

}

TY - JOUR

T1 - Activation of a cyclobutanone carbon-carbon bond over an aldehyde carbon-hydrogen bond in the rhodium-catalyzed decarbonylation

AU - Matsuda, Takanori

AU - Shigeno, Masanori

AU - Murakami, Masahiro

PY - 2006/3/5

Y1 - 2006/3/5

N2 - A rhodium(I)-N-heterocyclic carbene complex achieved a high-yield decarbonylation reaction of cyclobutanones to selectively afford cyclopropanes. With this catalyst, a cyclobutanone having an aldehyde moiety underwent chemoselective decarbonylation of the ketonic carbonyl group with the aldehydic carbonyl group left intact.

AB - A rhodium(I)-N-heterocyclic carbene complex achieved a high-yield decarbonylation reaction of cyclobutanones to selectively afford cyclopropanes. With this catalyst, a cyclobutanone having an aldehyde moiety underwent chemoselective decarbonylation of the ketonic carbonyl group with the aldehydic carbonyl group left intact.

UR - http://www.scopus.com/inward/record.url?scp=33744548526&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33744548526&partnerID=8YFLogxK

U2 - 10.1246/cl.2006.288

DO - 10.1246/cl.2006.288

M3 - Article

AN - SCOPUS:33744548526

SN - 0366-7022

VL - 35

SP - 288

EP - 289

JO - Chemistry Letters

JF - Chemistry Letters

IS - 3

ER -